The design, synthesis and mesomorphic properties of discotic liquid crystals

Followers
0

Organisation

University of Hull

There is no description for this organisation

License

© 2008 Philip Jeffrey Stackhouse. All rights reserved. No part of this publication may be reproduced without the written permission of the copyright holder.

The design, synthesis and mesomorphic properties of discotic liquid crystals

Discotic liquid crystal research is now more than 30 years old, however it is still early days compared with the well-established area of calamitic liquid crystal research which dates back for more than a century. Since the 1990’s there has been great deal of interest in discotic liquid crystal research, due to applications such as discotic compensation films for enhancing liquid crystal display (LCD) viewing angles and exciting new potential applications such as organic semi-conductors and photovoltaics.The work contained in this thesis can be broken down into three major areas: investigation of synthetic methodologies of hexasubstituted triphenylene-based discotic liquid crystals, examination of structure-property relationships within novel triphenylene-based discotic liquid crystalline materials, and the design and mesomorphic properties of novel disc-shaped molecular architectures.The investigation of the synthetic methodologies of triphenylene-based liquid crystals examined two main areas of the synthesis of triphenylene-based discotic materials: iodination reactions to generate valuable intermediates, and the oxidative strategies and methods for the generation of hexasubstituted triphenylenes. These investigations have revealed that careful control over reaction conditions can offer great selectivity in the synthesis of halogenated intermediates for the synthesis of triphenylene-based liquid crystals and that electron rich intermediate species offer the greatest scope for the synthesis of hexasubstituted triphenylenes in good yield and purity.The determination of structure-property relationships within triphenylene-based discotic liquid crystals has examined various peripheral substituents and various near-core modifications to the conventional discotic liquid crystal.A small number of novel spiral-shaped materials have been synthesised, which have revealed interesting mesomorphic properties. These materials have shown the ability to self-organise in such a manner as to fill free space around central disc units so as to generate columnar mesophases in materials which would not otherwise be expected to exhibit mesomorphism.

Data and Resources

Core Fields

Field Value
Metadata Created 27 January 2016, 18:11 (UTC)
creator
creator_identifier
creator_identifier_scheme
creator_affiliation
title_type
subject
subject_scheme
subject_scheme_identifier
keywords
geo_location
geo_location_point
geo_location_box
geo_location_place
format
unique_resource_identifier
publisher
publisher_identifier
project
funder_name
funder_id
date
date_type
rights
license_name
license_uri
access
resource_type
resource_type_additional
contact
contact_email
language
related_identifier
related_identifier_type
relation_type
image_thumbnail
metadata_created
metadata_license

Additional Info

Field Value
Maintainer Department of Physical Sciences, The University of Hull
Last Updated 12 June 2017, 16:28 (UTC)
http_access_status All Resources Available

Citation

The design, synthesis and mesomorphic properties of discotic liquid crystals. oai-hull-ac-uk-hull-1360